Study Notes On Curtius Rearrangement
The thermal decomposition of an acyl azide in presence of an inert solvent yields isocyanate as a major intermediate, along with nitrogen gas. The obtained isocyanate then undergoes further reaction in presence of water, alcohols, and amines to yield primary amine, carbamate, or urea derivatives, respectively.
General reaction-
Mechanism Of Curtius Reaction
Decomposition:
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